Tannin polyphenols are produced by plants to protect themselves against natural decay. It is expected that impregnating low-durable timber with tannin extracts of more durable species such as quebracho (Schinopsis balansae) will enhance the durability of the specimens. This biomimetic approach combined with the in situ polymerization of quebracho–hexamine formulations can be a valid alternative to synthetic wood preservatives. In this work, we aim to evaluate the impregnation mechanism as well as the impact of tannin and hardener concentration on the mechanical and leaching resistance properties of treated wood. Compression resistance, surface hardness and leaching resistance of four different common non-durable wood species: spruce (Picea abies), pine (Pinus spp.), poplar (Populus alba) and beech (Fagus sylvatica) impregnated with different concentrations of extract and hexamine are presented. The results show that the mechanical properties of tannin-impregnated timber are enhanced, especially for timber with lower densities. Tannin and hardener concentrations tendentially do not contribute significantly to further increase MOE (modulus of elasticity), MOR (modulus of rupture) and Brinell hardness. Similar results are also obtained when the specimens are tested against leaching: tannin is significantly more water-resistant when cured with hexamine, but higher amounts of hardener do not further improve its water resistance. These findings suggest that quebracho tannin–hexamine formulations are already effective at low concentrations (5 to 10% extract with 2.5 to 5% hexamine).
Quebracho-based wood preservatives: Effect of concentration and hardener on timber properties
Emanuele CespriniData Curation
;Tiziana UrsoMethodology
;Michela ZanettiResources
;Gianluca Tondi
Conceptualization
2022
Abstract
Tannin polyphenols are produced by plants to protect themselves against natural decay. It is expected that impregnating low-durable timber with tannin extracts of more durable species such as quebracho (Schinopsis balansae) will enhance the durability of the specimens. This biomimetic approach combined with the in situ polymerization of quebracho–hexamine formulations can be a valid alternative to synthetic wood preservatives. In this work, we aim to evaluate the impregnation mechanism as well as the impact of tannin and hardener concentration on the mechanical and leaching resistance properties of treated wood. Compression resistance, surface hardness and leaching resistance of four different common non-durable wood species: spruce (Picea abies), pine (Pinus spp.), poplar (Populus alba) and beech (Fagus sylvatica) impregnated with different concentrations of extract and hexamine are presented. The results show that the mechanical properties of tannin-impregnated timber are enhanced, especially for timber with lower densities. Tannin and hardener concentrations tendentially do not contribute significantly to further increase MOE (modulus of elasticity), MOR (modulus of rupture) and Brinell hardness. Similar results are also obtained when the specimens are tested against leaching: tannin is significantly more water-resistant when cured with hexamine, but higher amounts of hardener do not further improve its water resistance. These findings suggest that quebracho tannin–hexamine formulations are already effective at low concentrations (5 to 10% extract with 2.5 to 5% hexamine).File | Dimensione | Formato | |
---|---|---|---|
2022-Baccini_Coatings.pdf
accesso aperto
Tipologia:
Published (publisher's version)
Licenza:
Creative commons
Dimensione
27.52 MB
Formato
Adobe PDF
|
27.52 MB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.