Knowledge of the mechanism by which polymorphic inorganic species, such as carbonates, are formed is crucial to understand and guide the selective crystallization of end products. Recently it has been shown that a key step in the crystallization of calcium carbonate is the formation of intermediate species known as prenucleation clusters. However, the observation of these prenucleation clusters in solution is exceedingly challenging because of their short lifetime and low concentrations. Here, using dissolution DNP-enhanced NMR spectroscopy, we observe signals from prenucleation species of calcium carbonate from which the kinetics of formation and conversion are determined.

Observation of Transient Prenucleation Species of Calcium Carbonate by DNP-Enhanced NMR

Stevanato, Gabriele;
2024

Abstract

Knowledge of the mechanism by which polymorphic inorganic species, such as carbonates, are formed is crucial to understand and guide the selective crystallization of end products. Recently it has been shown that a key step in the crystallization of calcium carbonate is the formation of intermediate species known as prenucleation clusters. However, the observation of these prenucleation clusters in solution is exceedingly challenging because of their short lifetime and low concentrations. Here, using dissolution DNP-enhanced NMR spectroscopy, we observe signals from prenucleation species of calcium carbonate from which the kinetics of formation and conversion are determined.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3522932
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