A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions
Tang P.;Paganelli S.;Carraro F.;Blanco M.;Marega C.;Badocco D.;Pastore P.;Doonan C. J.;Agnoli S.
2020
Abstract
A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
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