In thiscontributionwereporton light-inducedmetal-freecouplingof propynylbenzenemolecularunitsonhighlyorientedpyrolyticgraphite.The reactionoccurswithinthe self-assembledmonolayerandleadsto the generationof covalentlycoupled1,5-hexadiyneandpara terphenylderivativesundertopologicalcontrol. Such photochemical uncatalysed pathway represents an original approachin the fieldof topological C-C coupling at the solid/liquid interface and provides new insight into the low temperature formation of aromatic compounds at the surface of carbonaceous supports.
On-surface Photochemistry of Pre-ordered 1-Methyl-2-phenyl-acetylenes: C-H Bond Activation and Intermolecular Coupling on Highly Oriented Pyrolytic Graphite
Casarin M.Investigation
;Sambi M.Investigation
;Sedona F.
Investigation
2019
Abstract
In thiscontributionwereporton light-inducedmetal-freecouplingof propynylbenzenemolecularunitsonhighlyorientedpyrolyticgraphite.The reactionoccurswithinthe self-assembledmonolayerandleadsto the generationof covalentlycoupled1,5-hexadiyneandpara terphenylderivativesundertopologicalcontrol. Such photochemical uncatalysed pathway represents an original approachin the fieldof topological C-C coupling at the solid/liquid interface and provides new insight into the low temperature formation of aromatic compounds at the surface of carbonaceous supports.File in questo prodotto:
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