Electrochemically mediated atom transfer radical polymerization ( e ATRP) is an advanced method to produce well-defined polymers. In e ATRP, an electric current is used to trigger the polymerization, (re)generate the active catalyst, and strictly control the process. This review describes the fundamentals of e ATRP and its applications to prepare homopolymers, block copolymers, star polymers, and surface-grafted polymer brushes.
Electrochemical triggering and control of atom transfer radical polymerization
Lorandi, Francesca;Fantin, Marco;Isse, Abdirisak Ahmed
;Gennaro, Armando
2018
Abstract
Electrochemically mediated atom transfer radical polymerization ( e ATRP) is an advanced method to produce well-defined polymers. In e ATRP, an electric current is used to trigger the polymerization, (re)generate the active catalyst, and strictly control the process. This review describes the fundamentals of e ATRP and its applications to prepare homopolymers, block copolymers, star polymers, and surface-grafted polymer brushes.
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