The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)4(OMc)12 (OMc = CH2[double bond, length as m-dash]CH(CH3)COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.
A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium (IV) dicarboxylates
GROSS, SILVIA
;
2010
Abstract
The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)4(OMc)12 (OMc = CH2[double bond, length as m-dash]CH(CH3)COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.
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