Two pH-sensitive stable nitroxide radicals are characterized by EPR spectroscopy and cyclic voltammetry in aqueous solution at different pH values. The rates of the photochemically-induced electron transfer reactions from the protonated and deprotonated forms of the radicals to a ruthenium complex are determined.
Electron transfer in pH-sensitive nitroxide radicals
BARBON, ANTONIO
Conceptualization
;BORTOLUS, MARCOInvestigation
;AHMED ISSE, ABDIRISAKInvestigation
;
2016
Abstract
Two pH-sensitive stable nitroxide radicals are characterized by EPR spectroscopy and cyclic voltammetry in aqueous solution at different pH values. The rates of the photochemically-induced electron transfer reactions from the protonated and deprotonated forms of the radicals to a ruthenium complex are determined.
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