In this study, we reported the phytochemical composition of the aerial parts of Atriplex halimus L. collected from Sardinia. This species is a halophytic shrub, typical of the Mediterranean Basin. Four new glycosylated flavonoids were isolated and their structures were elucidated on the basis of 1D, 2D NMR and MS spectra as 3′,5′-dimethoxymyricetin-3-O-β-d- xylopyranosyl-7-O-fucopyranosyl-(1 → 3)-β-d-glucopyranoside (1), 3′-methoxyquercetin-7-O-β-d-fucopyranosyl-(1 → 3)-β-d-glucopyranosyl-3-O-β-xylopyranosyl-(1 → 4)-β-xylopyranoside (2), 3′-methoxyquercetin-7-O-l-rhamnopyranosyl-3- O-arabinofuranosyl-(1 → 6)-β-d-glucopyranoside (3) and 3′,5′-dimethoxymyricetin-7-O-fucopyranosyl-(1 → 3)-β-d-glucopyranoside (4). LC-MSn analysis on the extract revealed the presence of other myricetin, quercetin, isorhamnetin glycosides, simple phenolic acids and esters.
Phytochemical investigation on Atriplex halimus L. from Sardinia
CLAUSER, MARIA;DALL'ACQUA, STEFANO;INNOCENTI, GABBRIELLA
2013
Abstract
In this study, we reported the phytochemical composition of the aerial parts of Atriplex halimus L. collected from Sardinia. This species is a halophytic shrub, typical of the Mediterranean Basin. Four new glycosylated flavonoids were isolated and their structures were elucidated on the basis of 1D, 2D NMR and MS spectra as 3′,5′-dimethoxymyricetin-3-O-β-d- xylopyranosyl-7-O-fucopyranosyl-(1 → 3)-β-d-glucopyranoside (1), 3′-methoxyquercetin-7-O-β-d-fucopyranosyl-(1 → 3)-β-d-glucopyranosyl-3-O-β-xylopyranosyl-(1 → 4)-β-xylopyranoside (2), 3′-methoxyquercetin-7-O-l-rhamnopyranosyl-3- O-arabinofuranosyl-(1 → 6)-β-d-glucopyranoside (3) and 3′,5′-dimethoxymyricetin-7-O-fucopyranosyl-(1 → 3)-β-d-glucopyranoside (4). LC-MSn analysis on the extract revealed the presence of other myricetin, quercetin, isorhamnetin glycosides, simple phenolic acids and esters.Pubblicazioni consigliate
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