Plasmonic substrates were prepared by electrophoretic deposition of Ag nanoparticles on SiO2/Si(100). The Ag nanoparticles were obtained using [Ag(NH3)(2)](+) U C as the Ag precursor and D-glucose as the reducing agent. Under optimized conditions, this simple and green synthesis method furnished a suspension of Ag nanoparticles with a narrow dimensional dispersion (centered around 27 nm) and a negative z-potential, suitable for electrophoretic deposition. Samples were chemically, optically and morphologically characterized by photoemission and UV-vis spectroscopy and electron microscopy, and tested as substrates for surface enhanced Raman spectroscopy. Despite being a very simple procedure, good enhancement factors were measured thanks to the formation of hot spots, formed by sandwiching the analyte (benzenethiol) between sequentially deposited Ag nanoparticles.

Green synthesis and electrophoretic deposition of Ag nanoparticles on SiO2/Si(100)

GIALLONGO, GIUSEPPE;RIZZI, GIAN-ANDREA;WEBER, VERENA;SIGNORINI, RAFFAELLA;GRANOZZI, GAETANO
2013

Abstract

Plasmonic substrates were prepared by electrophoretic deposition of Ag nanoparticles on SiO2/Si(100). The Ag nanoparticles were obtained using [Ag(NH3)(2)](+) U C as the Ag precursor and D-glucose as the reducing agent. Under optimized conditions, this simple and green synthesis method furnished a suspension of Ag nanoparticles with a narrow dimensional dispersion (centered around 27 nm) and a negative z-potential, suitable for electrophoretic deposition. Samples were chemically, optically and morphologically characterized by photoemission and UV-vis spectroscopy and electron microscopy, and tested as substrates for surface enhanced Raman spectroscopy. Despite being a very simple procedure, good enhancement factors were measured thanks to the formation of hot spots, formed by sandwiching the analyte (benzenethiol) between sequentially deposited Ag nanoparticles.
2013
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2806118
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