Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti pre-catalyst. The alcohol coordination has a twofold action: it switches the Ti peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.
Non-covalent Activation of a Titanium(IV) Oxygen-Transfer Catalyst
ZONTA, CRISTIANO;LICINI, GIULIA MARINA
2013
Abstract
Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti pre-catalyst. The alcohol coordination has a twofold action: it switches the Ti peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.File in questo prodotto:
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