Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti pre-catalyst. The alcohol coordination has a twofold action: it switches the Ti peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.

Non-covalent Activation of a Titanium(IV) Oxygen-Transfer Catalyst

ZONTA, CRISTIANO;LICINI, GIULIA MARINA
2013

Abstract

Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti pre-catalyst. The alcohol coordination has a twofold action: it switches the Ti peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2667078
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