Critically evaluated rate coefficients and confidence limits, with derived Arrhenius parameters and confidence ellipses, are reported for the propagation rate coefficients of styrene and methyl methacrylate at low conversion in bulk. Data were obtained by pulsed-laser polymerization in several laboratories, and obey the consistency criteria established for this technique. These results provide useful “benchmarks” for measurements of propagation rate coefficients by other workers and other techniques.
CRITICALLY-EVALUATED PROPAGATION RATECOEFFICIENTS IN FREE RADICALPOLYMERIZATIONSI. STYRENE AND METHYL METHACRYLATE
MASCHIO, GIUSEPPE;
1996
Abstract
Critically evaluated rate coefficients and confidence limits, with derived Arrhenius parameters and confidence ellipses, are reported for the propagation rate coefficients of styrene and methyl methacrylate at low conversion in bulk. Data were obtained by pulsed-laser polymerization in several laboratories, and obey the consistency criteria established for this technique. These results provide useful “benchmarks” for measurements of propagation rate coefficients by other workers and other techniques.
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