The stoichiometry and kinetics of the reaction of carbon monoxide with [CoI2(CO)(PEt3)2] were examined in different solvents and in the presence of free PEt3. The results are interpreted in terms of a mechanism in which an iodide-bridged dicobalt species undergoes carbon monoxide addition to give an intermediate which is reduced by external PEt3. © 1982.
Reductive carbonylation of Phosphino-complexes of cobalt(II), a kinetic investigation
BASATO, MARINO;
1982
Abstract
The stoichiometry and kinetics of the reaction of carbon monoxide with [CoI2(CO)(PEt3)2] were examined in different solvents and in the presence of free PEt3. The results are interpreted in terms of a mechanism in which an iodide-bridged dicobalt species undergoes carbon monoxide addition to give an intermediate which is reduced by external PEt3. © 1982.
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