Stable dicarbonyl(cycloocta-1,5-diene)(eta1-indenyl)iridium is formed by addition of CO to cyclooctadiene(eta5-indenyl)iridium in CD2Cl2 at low temperature. On raising the temperature above 250 K, the eta1 species changes quantitatively into dicarbonyl(eta5 -indenyl)iridium.
A stable dicarbonyl(cycloocta-1,5-diene)-(η1-indenyl)iridium intermediate in the substitution reaction of cycloocta-1,5-diene(η5-indenyl)iridium with carbon monoxide
CECCON, ALBERTO;SANTI, SAVERIO;
1993
Abstract
Stable dicarbonyl(cycloocta-1,5-diene)(eta1-indenyl)iridium is formed by addition of CO to cyclooctadiene(eta5-indenyl)iridium in CD2Cl2 at low temperature. On raising the temperature above 250 K, the eta1 species changes quantitatively into dicarbonyl(eta5 -indenyl)iridium.
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