Depending upon the diene, phenyl(tolyl-sulfonyl)acetylene afffords the (4+2), the (2+2)-cycloadducts or products derived by 1,4-addition of the two fragments from homolytic cleavage of the carbon-sulfur bond.
Reactivity of Phenyl(tolylsulfonyl)acetylene Towards Dienes and Homo-dienes - Cyclo-additions Versus Fragmentation-addition Reactions
LICINI, GIULIA MARINA;
1988
Abstract
Depending upon the diene, phenyl(tolyl-sulfonyl)acetylene afffords the (4+2), the (2+2)-cycloadducts or products derived by 1,4-addition of the two fragments from homolytic cleavage of the carbon-sulfur bond.
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