Oxidation of dinaphtho[2,1-d:1′,2′-f][1,3]dithiepine (2) gives a single diastereoisomeric sulphoxide (1) which reacts diastereospecifically with electrophiles at variance with the unoxidized substrate (2) and other combinations of oxides (4),(6), and (7) which afford diastereoisomeric mixtures of products.
Atropisomeric Sulfur-compounds In Organic-synthesis - Generation and Reactions of the Carbanions of Dinaphtho[2,1-d-1',2'-f][1,3]dithiepine and Its Oxides
LICINI, GIULIA MARINA
1989
Abstract
Oxidation of dinaphtho[2,1-d:1′,2′-f][1,3]dithiepine (2) gives a single diastereoisomeric sulphoxide (1) which reacts diastereospecifically with electrophiles at variance with the unoxidized substrate (2) and other combinations of oxides (4),(6), and (7) which afford diastereoisomeric mixtures of products.
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