Two benzyl groups can be assembled with a chiral shape in the 6H,12H-Dibenzo[bf][1,5]dithiocine structure which can be resolved into its antipods via enantioselective oxidation to the bissulfoxide. The latter affords one single diastereoisomer in the methylation of its bis-anion. The two sulfur atoms serve as linking agents, holder and transmitter of chirality, and activating functionalities.
Assembling Synthons In A Chiral Form - Equivalence of 6h,12h-dibenzo[b,f][1,5]dithiocin-s,s'-dioxide To 2 Chiral Benzyl Units
LICINI, GIULIA MARINA
1992
Abstract
Two benzyl groups can be assembled with a chiral shape in the 6H,12H-Dibenzo[bf][1,5]dithiocine structure which can be resolved into its antipods via enantioselective oxidation to the bissulfoxide. The latter affords one single diastereoisomer in the methylation of its bis-anion. The two sulfur atoms serve as linking agents, holder and transmitter of chirality, and activating functionalities.
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