We have studied the motion of the methyl group in the free radical obtained by gamma-irradiation of 4-methyl-2,6-di-t-butylphenol. The ENDOR spectra have been measured in thetemperature range 6 to 200 K. The height of hindering potential barrier has been obtained from the shift of the ENDOR lines at low temperature.
An ENDOR study of methyl dynamics at low temperature
BRUSTOLON, MARINA ROSA;MANIERO, ANNA LISA;
1992
Abstract
We have studied the motion of the methyl group in the free radical obtained by gamma-irradiation of 4-methyl-2,6-di-t-butylphenol. The ENDOR spectra have been measured in thetemperature range 6 to 200 K. The height of hindering potential barrier has been obtained from the shift of the ENDOR lines at low temperature.
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