The reaction of isocyanides, CNR, with hydroxy- and methoxy-alkyl complexes of platinum(II), PtOH(R)(Ph2PCH=CHPPh2)_and PtOCH3(R)(Ph2PCH=CHPPh2) (R = CF3, CH2 CN) affords insertion products Pt(CONHR)(R)(Ph2PCH=CHPPh2) and Pt[C(OCH3)=NR] (R)(Ph2PCH=CHPPh2) containing the carboxamido and imidoyl moiety, respectively.
Isocyanide insertion into platinum-oxygen bonds
MICHELIN, RINO;ROS, RENZO
1979
Abstract
The reaction of isocyanides, CNR, with hydroxy- and methoxy-alkyl complexes of platinum(II), PtOH(R)(Ph2PCH=CHPPh2)_and PtOCH3(R)(Ph2PCH=CHPPh2) (R = CF3, CH2 CN) affords insertion products Pt(CONHR)(R)(Ph2PCH=CHPPh2) and Pt[C(OCH3)=NR] (R)(Ph2PCH=CHPPh2) containing the carboxamido and imidoyl moiety, respectively.
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