The protonolysis of the Pt-C bond in trans-[PtH(CH2CN)(PPh3)2] in methanol/1,2- dichloroethane is shown to take place by a two step mechanism involving oxidative addition to the metal center followed by reductive elimination of CH3CN to give trans-[PtHCl(PPh3)2].
Protonolysis of the Pt-C bond in trans-[PtH(CH2CN)(PPh3)2]
MICHELIN, RINO;BELLUCO, UMBERTO;ROS, RENZO
1979
Abstract
The protonolysis of the Pt-C bond in trans-[PtH(CH2CN)(PPh3)2] in methanol/1,2- dichloroethane is shown to take place by a two step mechanism involving oxidative addition to the metal center followed by reductive elimination of CH3CN to give trans-[PtHCl(PPh3)2].
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