The preparation of some new organometallic derivatives of rhodium(III), obtained by the reaction of [Rh(CO)2Cl]2 with benzoyl azide in C5H6 or THF, are described. The chemical behaviour and IR and NMR data for the adducts with triphenylphosphine, p-toluidine, pyridine and 3,4-lutidine of formula [Rh(C6H4CONH)L(CO)Cl] show that they can be considered as benzoylimido derivatives of rhodium(III).
Reactions of organic azides with noble metal carbonyl halides
MICHELIN, RINO;
1975
Abstract
The preparation of some new organometallic derivatives of rhodium(III), obtained by the reaction of [Rh(CO)2Cl]2 with benzoyl azide in C5H6 or THF, are described. The chemical behaviour and IR and NMR data for the adducts with triphenylphosphine, p-toluidine, pyridine and 3,4-lutidine of formula [Rh(C6H4CONH)L(CO)Cl] show that they can be considered as benzoylimido derivatives of rhodium(III).
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