Four low-cost oxidants have been tested in the oxidation of olefins catalyzed by either [(diphoe)Pt(CF3)(CH2Cl2)]BF4 or [(diphoe)Pt(CF3)(OH)] (diphoe = cis-1,2-bis(diphenylphosphino)ethylene) under mild conditions. These include sodium hypochlorite, sodium perborate, tert-butyl hydroperoxide, and potassium hydroperoxysulfate (caroate).
Selective Oxidations of Olefins Catalyzed By Platinum(II) Complexes - Use of Tert-butyl Hydroperoxide and Potassium Caroate As Oxidants - Ketone Vs Epoxide Formation
TASSAN, AUGUSTO;MICHELIN, RINO
1989
Abstract
Four low-cost oxidants have been tested in the oxidation of olefins catalyzed by either [(diphoe)Pt(CF3)(CH2Cl2)]BF4 or [(diphoe)Pt(CF3)(OH)] (diphoe = cis-1,2-bis(diphenylphosphino)ethylene) under mild conditions. These include sodium hypochlorite, sodium perborate, tert-butyl hydroperoxide, and potassium hydroperoxysulfate (caroate).
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