A new type of ligating behaviour of the phosphirene ring system PPhCPh=CPh is described, in which novel dimeric platinum(II) chlorophosphane complexes result from phosphirene ring opening and a Pt-Cl bond-insertion reaction.
Novel Ring-opening and Halogen Transfer From Platinum(II) To Phosphorus In the Reaction of [PtCl2(CNR)2] (R = Bu-t, p-MeOC6H4) With the Phosphirene Ring PPhCPh=CPh - Crystal and Molecular-structure of the Dimeric Chlorophosphane Complex [PtCl(PClPhCPh=CPh)(CNBu-t)]2
MICHELIN, RINO;
1993
Abstract
A new type of ligating behaviour of the phosphirene ring system PPhCPh=CPh is described, in which novel dimeric platinum(II) chlorophosphane complexes result from phosphirene ring opening and a Pt-Cl bond-insertion reaction.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
