The crystal structure of (C6H5)3SnCH2CHCH2 has been determined. The asymmetric unit consists of two molecules of triphenylallyltin having virtually the same conformation. Their geometrical parameters exclude pπ-dπ bonding between the metal and the allyl double bond, and seem to be in a better agreement with a σ-π conjugation effect
THE CRYSTAL-STRUCTURE OF TRIPHENYLALLYLTIN
FURLANI, DONATELLA;MARTON, DANIELE;TAGLIAVINI, GIUSEPPE;
1985
Abstract
The crystal structure of (C6H5)3SnCH2CHCH2 has been determined. The asymmetric unit consists of two molecules of triphenylallyltin having virtually the same conformation. Their geometrical parameters exclude pπ-dπ bonding between the metal and the allyl double bond, and seem to be in a better agreement with a σ-π conjugation effect
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