The set of non-orthogonal functions D j pq (Ω) P1/2(Ω), in which the Wigner rotation functions are multiplied by the equilibrium orientational distribution, is shown to provide a convenient basis for the solution of the rotational diffusion problem in anisotropic liquids,in the entire range of orientational ordering.
A modified wigner function set for the Smoluchowski operator representation in anisotropic liquids
MORO, GIORGIO;NORDIO, PIER LUIGI
1983
Abstract
The set of non-orthogonal functions D j pq (Ω) P1/2(Ω), in which the Wigner rotation functions are multiplied by the equilibrium orientational distribution, is shown to provide a convenient basis for the solution of the rotational diffusion problem in anisotropic liquids,in the entire range of orientational ordering.
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