The skeleton of carbon suboxide remains intact on reaction with two platinum complexes. With (PPh3)2Pt(C2H4) the metallacyclopropane (1) is formed; with (PPh3)2Pt(O2) the dioxametallacyclopentane (2).
Reactions of carbon suboxide with platinum(0) complexes.
PANDOLFO, LUCIANO
1981
Abstract
The skeleton of carbon suboxide remains intact on reaction with two platinum complexes. With (PPh3)2Pt(C2H4) the metallacyclopropane (1) is formed; with (PPh3)2Pt(O2) the dioxametallacyclopentane (2).
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