The -carbido dimer [(PcFe)2C] and its derivatives of formula [((L)PcFe)2C] (L = acetone, pyridine, 4-methylpyridine, 1- methylimidazole, piperidine) have been prepared and studied by IR, Mossbauer, EPR, and NMR spectroscopy and magnetic susceptibility determinations. All of the complexes appear to contain Fe(IV).
High Valent Iron Phthalocyanine Five- and Six-coordinated m-Carbido Dimers.,
RUSSO, UMBERTO;ZANONATO, PIER LUIGI
1989
Abstract
The -carbido dimer [(PcFe)2C] and its derivatives of formula [((L)PcFe)2C] (L = acetone, pyridine, 4-methylpyridine, 1- methylimidazole, piperidine) have been prepared and studied by IR, Mossbauer, EPR, and NMR spectroscopy and magnetic susceptibility determinations. All of the complexes appear to contain Fe(IV).
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