An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or P-n-Bu3 at room temperature to give the thermodynamically unstable bis-substituted trans -[Pt(OAc)2L2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)2(PPh3)2] has been determined by X-ray analysis.
Reaction of platinum acetate with phosphines and molecular structure of trans-[Pt(OAc)(2)(PPh3)(2)]
BASATO, MARINO;BIFFIS, ANDREA;MARTINATI, GIANLUCA;TUBARO, CRISTINA;
2003
Abstract
An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or P-n-Bu3 at room temperature to give the thermodynamically unstable bis-substituted trans -[Pt(OAc)2L2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)2(PPh3)2] has been determined by X-ray analysis.
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