The complexes of formula [Fe(Pc)(diazole)(2)]. nH(2)O (Pc = phthalocyaninato dianion; diazole = pyrazole, 3(5)-methylpyrazole, indazole and 1-phenylimidazole) have been prepared and characterized. The Mossbauer spectra of the bisadducts of [Fe(Pc)] with diazoles show values of isomer shift close to those of the corresponding complexes with pyridines, but somewhat smaller values of quadrupole splitting
Complex of phthalocyaninatoiron(II) with diazoles
ETTORRE, RENATO;MARTON, DANIELE;RUSSO, UMBERTO;ZANONATO, PIER LUIGI
2001
Abstract
The complexes of formula [Fe(Pc)(diazole)(2)]. nH(2)O (Pc = phthalocyaninato dianion; diazole = pyrazole, 3(5)-methylpyrazole, indazole and 1-phenylimidazole) have been prepared and characterized. The Mossbauer spectra of the bisadducts of [Fe(Pc)] with diazoles show values of isomer shift close to those of the corresponding complexes with pyridines, but somewhat smaller values of quadrupole splitting
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