The copper (II) acrylic monomer Cu(aaem)2 (aaem = 2-acetoacetoxyethyl methacrylate) undergoes high-yield γ-ray copolymerization with dimethylacrylamide, styrene, and hydroxoethyl methacrylate in the presence of methylene bisacrylamide as crosslinking agent in dimethylformamide. The metalloorganic copolymers are fully characterized. Polymer-protected Cu(II) results in being extremely stable toward a number of reducing agents in different media.
High yield gamma ray-induced polymerisation of bis-2-acetoacetoxyethylmethacrylate copper(II)
ZECCA, MARCO;PALMA, GIANCARLO;CORAIN, BENEDETTO
1997
Abstract
The copper (II) acrylic monomer Cu(aaem)2 (aaem = 2-acetoacetoxyethyl methacrylate) undergoes high-yield γ-ray copolymerization with dimethylacrylamide, styrene, and hydroxoethyl methacrylate in the presence of methylene bisacrylamide as crosslinking agent in dimethylformamide. The metalloorganic copolymers are fully characterized. Polymer-protected Cu(II) results in being extremely stable toward a number of reducing agents in different media.
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