Molybdenum was deposited in two steps (3 eq. ML and 1 eq. ML) on the light blue rutile TiO2(1 1 0) (1 × 1) surface at room temperature, each Mo deposition cycle being followed by an annealing up to 950–1000 K. This procedure was found to lead to formation of separated clusters having a size in very wide range (1–20 nm). Scanning tunneling microscopy showed a dependence of the cluster morphology as a function of the size. The scanning tunneling spectra of Mo clusters was studied as a function of cluster dimensions and discussed in comparison with photoelectron spectroscopy results previously obtained for homogeneous Mo films. The dI/dV curves do not display the valence band structure of deposited material, which could be explained by the Schottky barrier formation.
Scanning Tunneling microscopy and spectroscopy of Mo clusters grown on TiO2(110)
RIZZI, GIAN-ANDREA;GRANOZZI, GAETANO;
2007
Abstract
Molybdenum was deposited in two steps (3 eq. ML and 1 eq. ML) on the light blue rutile TiO2(1 1 0) (1 × 1) surface at room temperature, each Mo deposition cycle being followed by an annealing up to 950–1000 K. This procedure was found to lead to formation of separated clusters having a size in very wide range (1–20 nm). Scanning tunneling microscopy showed a dependence of the cluster morphology as a function of the size. The scanning tunneling spectra of Mo clusters was studied as a function of cluster dimensions and discussed in comparison with photoelectron spectroscopy results previously obtained for homogeneous Mo films. The dI/dV curves do not display the valence band structure of deposited material, which could be explained by the Schottky barrier formation.
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