.Microstructure of a nitrided steel previously decarburized

In this study the effects of a surface-controlled decarburization on the structure of a nitrided steel are analyzed. Samples of a quenched and tempered 42CrMo4 steel were decarburized by heating in air at different depths and submitted to gaseous nitriding. After decarburization and nitriding, the microstructure of surface layers was investigated by optical microscopy (OM) and scanning electron microscopy (SEM). The nitrogen and carbon profiles in the diffusion layers were determined by SEM equipped with a wavelength dispersive spectrometer (EPMA-WDS) and by glow discharge optical spectrometry (GDOS). The effect of nitriding was determined by microhardness measurements. Our results indicate that a previous decarburization only slightly affects the surface hardness, but reduces the conventional nitriding depth. The decarburization also favors the nitrogen take-up and produces increased nitrogen concentrations in the compound layer and in the narrow zone beneath it.