Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1.
Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SIW10O36](8-): A totally inorganic oxygen-evolving catalyst
SARTOREL, ANDREA;CARRARO, MAURO;SCORRANO, GIANFRANCO;BONCHIO, MARCELLA
2008
Abstract
Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1.
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