Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1.

Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SIW10O36](8-): A totally inorganic oxygen-evolving catalyst

SARTOREL, ANDREA;CARRARO, MAURO;SCORRANO, GIANFRANCO;BONCHIO, MARCELLA
2008

Abstract

Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2434963
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 556
  • ???jsp.display-item.citation.isi??? 522
  • OpenAlex ND
social impact