The Cp ring in [RuCl(Cp)(PPh3)(2)] undergoes an apparent nucleophilic attack by the carbanion carb (Hcarb = 2-Me-1,2-dicarba-closo-dodecaborane), to give an H-/carb(-) exchange process, which is favoured by coordination of the hydride to the ruthenium centre.
Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion
BASATO, MARINO;BIFFIS, ANDREA;TUBARO, CRISTINA;
2004
Abstract
The Cp ring in [RuCl(Cp)(PPh3)(2)] undergoes an apparent nucleophilic attack by the carbanion carb (Hcarb = 2-Me-1,2-dicarba-closo-dodecaborane), to give an H-/carb(-) exchange process, which is favoured by coordination of the hydride to the ruthenium centre.File in questo prodotto:
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