Tunable electronic coupling in iron-chromium mixed-valence ions of methylated Cp-indene ligands

A series of heterobimetallic mu(6)-[(ferrocenyl) indene]-Cr(CO)(3) complexes differing for the position of the ferrocenyl group, 1-(ferrocenyl) indene and 2-(ferrocenyl) indene, and the degree of indene methylation (tetramethyl- and hexamethyl-) have been prepared and studied with the aim to stabilise the mono- and dications generated by chemical and electrochemical oxidation, and at same time to tune the metal-metal electronic coupling in the mixed- valence cations. The magnitude of electronic delocalisation and spin density in the cations have been monitored by means of optical techniques (UV-Vis, near-IR, mid-IR) and EPR spectroscopy. The results have been rationalised in the framework of Marcus-Hush theory and at quantum chemistry level by DFT and TD-DFT methods, establishing that a metal-to-metal electronic coupling occurs the magnitude of which depends on the degree of indene methylation.