A systematic analysis of the linkage isomerism of nitriles in half'sandwichfive-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods.
Linkage isomerism of nitriles in rhodium half-sandwich metallacycles
ORIAN, LAURA;
2008
Abstract
A systematic analysis of the linkage isomerism of nitriles in half'sandwichfive-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods.
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