The title catalyst belongs to a family of titanium complexes bearing C3-symmetric trialkanolamines ligands, which bind tightly to the Ti(IV) center in a tetradentate fashion providing very stable titanatranes. These complexes effect the enantioselective oxidation of prostereogenic sulfides in the presence of alkyl hydroperoxides
alpha,alpha',alpha"-[Nitrilo-N)tris(methylene)]tris[benzenemethanolato-O](2-propanolato)titanium
BONCHIO, MARCELLA;LICINI, GIULIA MARINA
2003
Abstract
The title catalyst belongs to a family of titanium complexes bearing C3-symmetric trialkanolamines ligands, which bind tightly to the Ti(IV) center in a tetradentate fashion providing very stable titanatranes. These complexes effect the enantioselective oxidation of prostereogenic sulfides in the presence of alkyl hydroperoxides
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