Selective hydroxylation (or ketonization) of cyclic alkanes and conversion of ether to esthers and of secondary alcohols to ketones, with significant rates (up to ca. 1 turnover per minute at room temperature), were achieved by using hypochlorite as oxidant and a choice of ruthenium (II) complexes as catalysts, in a biphasic water-dichloromethane system.
SELECTIVE OXIDATION OF ALKANES AND ETHERS MEDIATED BY RUTHENIUM(II) COMPLEXES
MORVILLO, ANTONINO
1989
Abstract
Selective hydroxylation (or ketonization) of cyclic alkanes and conversion of ether to esthers and of secondary alcohols to ketones, with significant rates (up to ca. 1 turnover per minute at room temperature), were achieved by using hypochlorite as oxidant and a choice of ruthenium (II) complexes as catalysts, in a biphasic water-dichloromethane system.File in questo prodotto:
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