In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.
IODOSOBENZENE AND PERSULFATE OXYGENATION OF SATURATED-HYDROCARBONS CATALYZED BY DIPHOSPHINO COMPLEXES OF RUTHENIUM(III)
MORVILLO, ANTONINO
1993
Abstract
In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.File in questo prodotto:
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