In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.
EFFECTIVE RUTHENIUM-CATALYZED OXIDATION OF CHLORINATED OLEFINS BY MONOPERSULFATE IN AQUEOUS-MEDIUM
MORVILLO, ANTONINO
1994
Abstract
In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.
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