The structural and electronic properties of the polymeric phase of Na2RbC60 which comprises of C-C bridged C-60(3-) chains have been studied between 410 and 4 K with the electron spin resonance (ESR) technique. On cooling, the polymeric phase starts growing below similar to 250 K. Its fraction reaches a maximum at similar to 190 K, where around 55% of the monomeric cubic phase have transformed to the polymer. The temperature dependence of the ESR susceptibility suggests that the Na2RbC60 polymer is conducting down to 3 K. The ESR results exclude the possibility of the existence of a ground-state instability and the formation of either a spin-density-wave (SDW) or a charge-densitywave (CDW) stat
Electron spin resonance study of the polymeric phase of Na2RbC60
MANIERO, ANNA LISA;
1999
Abstract
The structural and electronic properties of the polymeric phase of Na2RbC60 which comprises of C-C bridged C-60(3-) chains have been studied between 410 and 4 K with the electron spin resonance (ESR) technique. On cooling, the polymeric phase starts growing below similar to 250 K. Its fraction reaches a maximum at similar to 190 K, where around 55% of the monomeric cubic phase have transformed to the polymer. The temperature dependence of the ESR susceptibility suggests that the Na2RbC60 polymer is conducting down to 3 K. The ESR results exclude the possibility of the existence of a ground-state instability and the formation of either a spin-density-wave (SDW) or a charge-densitywave (CDW) stat
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