Monomeric η1-allyl complexes [PtCl(C3H5)(PSR)], (PSR = Ph2P(CH2)2SR, R = Me, Ph) are rapidly converted in polar media into the η3-allyl derivatives [Pt(C3H5)(PSR)]BF4. The NMR characteristics of both types of complex are discussed.
Allylplatinum and platinum(O) complexes with phosphorus-sulfur mixed ligands.
MORVILLO, ANTONINO
1986
Abstract
Monomeric η1-allyl complexes [PtCl(C3H5)(PSR)], (PSR = Ph2P(CH2)2SR, R = Me, Ph) are rapidly converted in polar media into the η3-allyl derivatives [Pt(C3H5)(PSR)]BF4. The NMR characteristics of both types of complex are discussed.
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