Reactions of active methylene compounds HA (malononitrile, β-diketones, cyclopentadiene) with the dioxygen adduct [Rh(dppe)O2]BF4 give new hydroperoxorhodium(III) complexes of the type [Rh(dppe)(A)OOH]BF4. The complexes readily convert PPh3 into OPPh3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization.

Reactions of methylene active compounds with peroxo-rhodium phosphino complexes. Formation of hydro-peroxorodhium complexes.

MORVILLO, ANTONINO;
1987

Abstract

Reactions of active methylene compounds HA (malononitrile, β-diketones, cyclopentadiene) with the dioxygen adduct [Rh(dppe)O2]BF4 give new hydroperoxorhodium(III) complexes of the type [Rh(dppe)(A)OOH]BF4. The complexes readily convert PPh3 into OPPh3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization.
1987
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/136384
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