Ruthenium(II) and osmium(II) complexes [MCl(LL)2]Y, were LL is 1,3-bis(diphenylphosphino)propane or 1-diphenilphosphino-2-(2'-pyridil)ethane, promote the oxidation of a number of alkenes by PhIO, hypochlorites, and H2O2.
Catalytic epoxidation of olefins by coordinatively unsaturated phosphino-complexes of ruthenium(II) and osmium(II).
MORVILLO, ANTONINO
1988
Abstract
Ruthenium(II) and osmium(II) complexes [MCl(LL)2]Y, were LL is 1,3-bis(diphenylphosphino)propane or 1-diphenilphosphino-2-(2'-pyridil)ethane, promote the oxidation of a number of alkenes by PhIO, hypochlorites, and H2O2.
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