The π-dienecobalt(I) derivatives [Co(diene)(P)3] (P = phosphine ligand) have been prepared by (1) reactions of conjugated dienes with Co(ClO4)2·6H2O and phosphine and (2) by treatment of the [CoH2(P)4]+ complexes with dienes.
Cationic complexes of cobalt(I) with phosphines and conjugated diolefines.
MORVILLO, ANTONINO
1975
Abstract
The π-dienecobalt(I) derivatives [Co(diene)(P)3] (P = phosphine ligand) have been prepared by (1) reactions of conjugated dienes with Co(ClO4)2·6H2O and phosphine and (2) by treatment of the [CoH2(P)4]+ complexes with dienes.
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