Complexes of the type [Co(CO)n(P)5−n]ClO4, [CoH2(P)4]ClO4, [CoH(P)5](ClO4)2 and [CoHX(F)4]ClO4 (P = secondary or tertiary phosphine) have been prepared from Co(ClO4)2·6 H2O and phosphine in isopropyl alcohol.
Cobalt(I) and cobalt(III) derivatives from the reactions of phosphine ligands with cobalt(II) salts containing low-coordinating anions.
MORVILLO, ANTONINO
1975
Abstract
Complexes of the type [Co(CO)n(P)5−n]ClO4, [CoH2(P)4]ClO4, [CoH(P)5](ClO4)2 and [CoHX(F)4]ClO4 (P = secondary or tertiary phosphine) have been prepared from Co(ClO4)2·6 H2O and phosphine in isopropyl alcohol.
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