Isocyanides ligating medium to high-valent electron-poor metal centers can undergo activation toward α-nucleophilic addition to afford a variety of aminocarbene complexes with either heterocyclic or acyclic aminocarbene ligands. These reactions as well as the structural and electronic properties of such products are reviewed. © 2001 Elsevier Science B.V.
Aminocarbene Complexes Derived from Nucleophilic Addition to Isocyanide Ligands
MICHELIN, RINO;
2001
Abstract
Isocyanides ligating medium to high-valent electron-poor metal centers can undergo activation toward α-nucleophilic addition to afford a variety of aminocarbene complexes with either heterocyclic or acyclic aminocarbene ligands. These reactions as well as the structural and electronic properties of such products are reviewed. © 2001 Elsevier Science B.V.
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