A new polymer has been shown to be an effective hydrogenation catalyst: specifically, the polymer that results from copolymerization (through γ- irradiation) of the isocyanide complex 1 with dimethylacrylamide in the presence of N,N′-methylenebisacrylamide. The Pd(II) centers are initially pre-hydrogenated to Pd0, after which the catalyst becomes stable, especially with respect to the loss of metallic centers.
RADIATION-INDUCED COPOLYMERIZATION OF CIS-[PDCL2(CN(CH2)3-OC(O)-CH=CH2)2] - A NOVEL ROUTE TO ORGANOMETALLIC CROSS-LINKED COPOLYMERS USEFUL FOR CATALYTIC APPLICATIONS
CORAIN, BENEDETTO;ZECCA, MARCO;PALMA, GIANCARLO;
1990
Abstract
A new polymer has been shown to be an effective hydrogenation catalyst: specifically, the polymer that results from copolymerization (through γ- irradiation) of the isocyanide complex 1 with dimethylacrylamide in the presence of N,N′-methylenebisacrylamide. The Pd(II) centers are initially pre-hydrogenated to Pd0, after which the catalyst becomes stable, especially with respect to the loss of metallic centers.
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