The title compound, C43H79O2NPt, crystallizes in the monoclinic system, space group P2(1)/c, with a = 20.444(8) angstrom, b = 12.220(4) angstrom, c = 18.303(7) angstrom, beta = 101.6(4), Z = 4. The coordination of Pt is slightly distorted square-planar, the backbone of the hydro-aldoamidic ligand is almost planar; its mean plane is orthogonal to the coordination plane of Pt. The crystal structure has been refined to R = 0.054 for 3518 observed reflections.
THE CRYSTAL-STRUCTURE OF PT(II)-TRANS-[(BIS-TRICYCLOHEXYLPHOSPHINE)-(ETA-1-HYDRO-FORMYL-TER-BUTYL AMIDO)(HYDRIDE)]
PANDOLFO, LUCIANO;
1991
Abstract
The title compound, C43H79O2NPt, crystallizes in the monoclinic system, space group P2(1)/c, with a = 20.444(8) angstrom, b = 12.220(4) angstrom, c = 18.303(7) angstrom, beta = 101.6(4), Z = 4. The coordination of Pt is slightly distorted square-planar, the backbone of the hydro-aldoamidic ligand is almost planar; its mean plane is orthogonal to the coordination plane of Pt. The crystal structure has been refined to R = 0.054 for 3518 observed reflections.
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