Carbon suboxide, C3O2, reacts with a great variety of organometallic compounds, yielding, with organosilicon and organoaluminum, sililation and carboalumination products, respectively. Insertion reactions of C=C are performed with compounds having M-H, M-OR, M-NR2, M-PR2 bonds, giving mono-meta derivatives (ketenyl) or di-metal derivatives. Ketenyl, ketenylidene and carbonyl complexes are also obtained.
THE ORGANOMETALLIC CHEMISTRY OF CARBON SUBOXIDE
PANDOLFO, LUCIANO
1991
Abstract
Carbon suboxide, C3O2, reacts with a great variety of organometallic compounds, yielding, with organosilicon and organoaluminum, sililation and carboalumination products, respectively. Insertion reactions of C=C are performed with compounds having M-H, M-OR, M-NR2, M-PR2 bonds, giving mono-meta derivatives (ketenyl) or di-metal derivatives. Ketenyl, ketenylidene and carbonyl complexes are also obtained.
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