The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and π-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agreement with this interpretation.
Experimental evidence at atomic resolution of intra- and intermolecular CO⋯π(arene) bond interactions
GAMBARO, ALESSANDRO;POLIMENO, ANTONINO;SANTI, SAVERIO;
1999
Abstract
The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and π-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agreement with this interpretation.
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